Over the past decade, Tim Bertram has led a highly collaborative and interdisciplinary team to address long-standing fundamental and applied questions in atmospheric chemistry. The core of Tim’s research program focuses on atmospheric chemical mechanisms occurring at aqueous interfaces, studied using combined laboratory and field-based approaches. These approaches have required the development of novel chemical instrumentation and the application of these techniques to unique scientific landscapes. These common themes are showcased by two persistent areas of research that Tim and his team lead. First, no single chemical reaction has remained as elusive to atmospheric chemists as the reaction of N2O5 at aqueous interfaces. This chemical reaction is as chemically fascinating as it is centrally important to urban air quality.
Through his role as the associate director of the National Science Foundation’s Center for Aerosol Impacts on Chemistry of the Environment (CAICE), Tim assembled a team to molecularly dissect this reaction mechanism at the atomic scale in order to reconstruct the essential elements in a way that could be robustly represented in global model simulations. This effort spans theoretical simulations, laboratory and field studies, and chemical transport model analyses. Second, the oxidation products of dimethyl sulfide (DMS), emitted from the ocean, play a central role in particle formation and growth in the remote marine environment. In a highly collaborative effort, Tim and his team redrew the oxidation mechanism for DMS, highlighting the critical role for cloud chemistry in short-circuiting the production of new cloud condensation nuclei. This work again spanned detailed laboratory studies coupled with field investigations, where Tim led a U.S. Department of Energy team to the Azores in 2022, and again the chemical mechanisms were distilled and implemented in chemical transport models to assess the significance on the global scale. But perhaps what is most notable about Tim and his team is their ability to distill the chemical complexity of real-world systems to reveal underlying and essential processes that control atmospheric composition.
—Gilbert Nathanson, University of Wisconsin–Madison
Nitrogen oxides (NOx) have adverse human health impacts and play a central role in the production of ozone and PM2.5. Nighttime heterogeneous chemi...